A Cyclic Peroxy Ester, β-Methyl-β-phenyl-β-peroxypropiolactone 1
✍ Scribed by Greene, Frederick D.; Adam, Waldemar; Knudsen, George A.
- Book ID
- 127370030
- Publisher
- American Chemical Society
- Year
- 1966
- Tongue
- English
- Weight
- 570 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Attempted epoxidation of long‐chain α,β‐unsaturated esters resulted in the formation of the rearranged products of the corresponding epoxyesters. It was observed that reaction of peracids with esters of C~16~, C~18~ and C~22~ trans‐2‐enoic acids, instead of yielding the expected epoxide
values of torsion angles È and É show the presence of two type III 0 -turns, at the Á Z Phe 2 and Gly 3 residues, and Gly 3 and Á Z Phe 4 residues. All amino acids in the peptide are linked trans to each other. Two intramolecular N-HÁ Á ÁO hydrogen bonds, between CO and NH groups, stabilize -turns p