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Photolysis of methyl ester of 1β,2β-epoxy-3-keto derivative of gibberellin A1

✍ Scribed by N. S. Kobrina; É. P. Serebryakov; V. F. Kucherov

Book ID
112423428
Publisher
Springer
Year
1972
Tongue
English
Weight
215 KB
Volume
21
Category
Article
ISSN
1573-9171

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✍ Stephen H. Bell; Donald W. Cameron; Geoffrey I. Feutrill; Brian W. Skelton; Alla 📂 Article 📅 1985 🏛 Elsevier Science 🌐 French ⚖ 287 KB

Spectroscopic analysis of the 1,1,3-trioxy dienes (l), (2) shows them to possess @)-stereochemistry, contrary to several literature assignments; characterisation of derived cycloadducts and crystallographic analysis of one of them (20) establishes endo cycloaddition. Cycloaddition of polyoxygenated