A Critical Review of Electronic Effects in Enediamido and α-Diimino Complexes of the Group 4 Metals
✍ Scribed by Carlo Mealli; Andrea Ienco; Andrew D. Phillips; Agustin Galindo
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 12 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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## Abstract In the presence of Ni^2+^ the template reaction between 2,6‐diacetylpyridine and 4‐(2‐dimethylaminoethyl)‐ or 4‐(2‐hydroxyethyl)‐1, 7‐diamino‐4‐azaheptane yields the complexes of either the open‐chain ligand (**3** and **11**) or of the macrocycle (**4** and **12**). Reduction of the im
## Abstract The two macrocycles 1‐(2‐aminoethyl)‐ and 1‐[2‐(dimethylamino)ethyl]‐4, 8, 11‐trimethyl‐1, 4, 8, 11‐tetraazacyclotetradecane, **1** and **2**, respectively, and their metal complexes with Co^2+^, Ni^2+^ and Cu^2+^ were prepared. The different spectral properties of the complexes with th