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A coupled cluster study of the electronic spectroscopy and photochemistry of Cr(CO)6

✍ Scribed by Villaume, Sébastien; Strich, Alain; Daniel, Chantal; Perera, S. Ajith; Bartlett, Rodney J.


Book ID
118208908
Publisher
Royal Society of Chemistry
Year
2007
Tongue
English
Weight
715 KB
Volume
9
Category
Article
ISSN
1463-9076

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Picosecond photochemistry of Cr(CO)6: So
✍ John D. Simon; Kevin S. Peters 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 442 KB

Picosecond absorption spectroscopy has been used to examine the primary pho~oprodact of Cr(CO), in both neat and mixtures of THF and cyclohexane. The primary intermediate observed is shown to be she solvated pentacarbanyl in uhich one solvent molecule occupies the coordination sire created by the ph