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A copper(II) complex of the Schiff base froml-valine and 2-hydroxy-1-naphthalidene plus 1,10-phenanthroline: synthesis, crystal structure, and DNA interaction

✍ Scribed by Jinghong Li; Jianfang Dong; Hui Cui; Tao Xu; Lianzhi Li

Publisher: Springer
Year: 2011
Tongue: English
Weight: 614 KB
Volume: 37
Category: Article
ISSN: 0340-4285
DOI: 10.1007/s11243-011-9572-1

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Blue crystals of Cu 2 (phen) 2 (H 2 O) 2 (C 5 H 6 O 4 ) 2 were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), glutaric acid and Na 2 CO 3 . The crystal structure (monoclinic, P2 1 /c (no. 14), a = 10.271(1), b = 10.595(1), c = 15.585(1) A Ê , b = 107.105(3)°,