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A Copper(I)-catalyzed photochemical cyclodimerization of 1, 3, 5-hexatriene

✍ Scribed by H. J. T. Bos; V. H. M. Elferink; D. van der Ploeg


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
127 KB
Volume
103
Category
Article
ISSN
0165-0513

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A two-dimensional potential-energy surface was calculated for the ground state of Z-1,3,5-hexatriene in order to study the conformational relaxation after its photochemical formation from 1,3-cyclohexadiene. The potential-energy surface was scanned along both C-C single bond torsional angles while a