A theoretical study of the structure and spectrum of 1,3,5-hexatriene
β Scribed by G.J. Mains; P. George; M. Trachtman; A.M. Brett; C.W. Bock
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 816 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0022-2860
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π SIMILAR VOLUMES
A two-dimensional potential-energy surface was calculated for the ground state of Z-1,3,5-hexatriene in order to study the conformational relaxation after its photochemical formation from 1,3-cyclohexadiene. The potential-energy surface was scanned along both C-C single bond torsional angles while a
Two-photon absorption spectra of trans-and cis-1,3,5-hexatriene in the liquid state have beet ob:erved in the frequency range of 20 = 3oooO-SO000 cm-t, by analyzing the interference effe& of Raman and two-photon resonances in the CARS and CSRS lineshape. In both isomers, a broad two-photon absorptio