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A convergent approach to indolines and indanes

✍ Scribed by Thi-My Ly; Béatrice Quiclet-Sire; Benoît Sortais; Samir Z. Zard

Book ID
104261080
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
231 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

Radical addition of a xanthate to an N-allylanilide or to a substituted 4-aryl-l-butene followed by cyclisadon onto the aromatic ring provide the corresponding indoline or indane respectively.

📜 SIMILAR VOLUMES

ChemInform Abstract: A Convergent Approa
ChemInform Abstract: A Convergent Approach to Indolines and Indans.
✍ Thi-My Ly; Beatrice Quiclet-Sire; Benoit Sortais; Samir Z. Zard 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB 👁 2 views

A Convergent Approach to Indolines and Indans. -Indolines and indans are available by radical addition of xanthates (II) to N-allylanilides (I) or a substituted 4-aryl-1-butene (V) followed by cyclization onto the aromatic ring.

A convergent approach to functionalised
A convergent approach to functionalised alkynes
✍ Jean Boivin; Sylvain Huppé; Samir Z Zard 📂 Article 📅 1996 🏛 Elsevier Science 🌐 French ⚖ 209 KB

Knoevenagel type condensation of 4-unsubstituted isoxazolinones with ketones or aldehydes followed by Michael addition of a nucleophile --hydride, cyanide, or phosphite--and exposure of the adduct to sodium nitrite / aqueous acetic acid and ferrous sulfate gives variously functionalised alkynes.