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A convenient synthesis of (Z)-1-chloro-1-alkenes and (Z)-1-chloro-2-alkoxy-1-alkenes

✍ Scribed by Rachid Baati; D.K. Barma; U.Murali Krishna; Charles Mioskowski; J.R. Falck

Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 70 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)02304-8

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✦ Synopsis

Mild, room temperature CrCl 2 reduction of 1,1,1-trichloroalkanes stereoselectively generates (Z)-1-chloro-2-substituted-1-alkenes in excellent yields.

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