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A CONVENIENT SYNTHESIS OF ISOPHYTOL BY CROSS-COUPLING REACTION OF A GRIGNARD REAGENT AND A PROTECTED ALLYLIC CHLORIDE

โœ Scribed by Miyakoshi, Tetsuo; Hagimoto, Mitsuhiro

Book ID
121295985
Publisher
Taylor and Francis Group
Year
1992
Tongue
English
Weight
458 KB
Volume
24
Category
Article
ISSN
0030-4948

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Iron catalyzed cross-coupling reactions
Iron catalyzed cross-coupling reactions of acyl chlorides with Grignard reagents. A mild, general, and convenient synthesis of aliphatic and aromatic ketones.
โœ V. Fiandanese; G. Marchese; V. Martina; L. Ronzini ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 197 KB

TABLE Cross-Coupling Reactions of Acyl Chlorides with Grignard Reagents in the Presence of Fe(acac)3 as a Catalysta. R-C+ 0 3% Fe(acac)3 0 + 'Cl R'MgXb THF R-C< R' Entry R R' Temp Yield in KetoneC % 1 CH3(Ct& CH3 r.t. 84 2 CH3(CH2)4 CH3(C"2)4 r.t. 82 3 CH3 CH3(CH2)8 r.t. 82 4 CH3 CH3(CH2)9 r.t. 80 5