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A convenient synthesis of glycals employing in-situ generated Cp2TiCl

✍ Scribed by Thomas Hansen; Sussie L. Krintel; Kim Daasbjerg; Troels Skrydstrup

Book ID
104262049
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
208 KB
Volume
40
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

Development of a catalytic cycle for the
Development of a catalytic cycle for the generation of C1-glycosyl carbanions with Cp2TiCl2: application to glycal synthesis
✍ Thomas Hansen; Kim Daasbjerg; Troels Skrydstrup πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 93 KB

A catalytic cycle has been developed for the conversion of glycosyl halides to their corresponding glycals using Cp 2 TiCl 2 . This process can be effectively used with only 30% of the in situ generated single electron reducing agent in contrast to the 2 equivalents normally employed.

ChemInform Abstract: Development of a Ca
ChemInform Abstract: Development of a Catalytic Cycle for the Generation of C1-Glycosyl Carbanions with Cp2TiCl2: Application to Glycal Synthesis.
✍ Thomas Hansen; Kim Daasbjerg; Troels Skrydstrup πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons βš– 32 KB πŸ‘ 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v