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A Convenient Synthesis of Chiral Oxazolidin-2-Ones and Thiazolidin-2-Ones and an Improved Preparation of Triphosgene

✍ Scribed by Falb, Eliezer; Nudelman, Abraham; Hassner, Alfred

Book ID
118269604
Publisher
Taylor and Francis Group
Year
1993
Tongue
English
Weight
235 KB
Volume
23
Category
Article
ISSN
0039-7911

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✍ SΓ­lvia Fonquerna; Albert Moyano; Miquel A. PericΓ s; Antoni Riera πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 English βš– 450 KB

Chiral 2-alkynoate derivatives of 4-substituted oxazolidin-2-ones and of Oppolzer's 10,2-camphorsultam have been synthesized in good to excellent yields using a one-pot method involving the nucleophilic attack of the lithium salt or the lithium chloride complex of the chiral auxiliary on a mixed 2-a