A CONVENIENT SYNTHESIS OF 2(5H)-FURANONE
β Scribed by Cao, Ruzhen; Liu, Chong; Liu, Lunzu
- Book ID
- 120475462
- Publisher
- Taylor and Francis Group
- Year
- 1996
- Tongue
- English
- Weight
- 120 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0030-4948
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
A convenient procedure for the preparation of 3-functionalized 5-aikoxymethyl-and 5phenoxymethyl-2(SH)-furanones is described. The method is basedonthe condensation of various p-alkoxy-or ~-phenoxy-a-hydroxy ketones with ~activated esters in the presence of catalytic amounts of sodium methoxide. Res
Starting fro enolizing 1.2~diketones 1 and (2,2dlathoxyvinylidene)triphenylphosphorane (1) or from 2 and (2.2-dlethoxyvlnyl)triphewlphosphonlu tetrafluorohorate (a) the orthoesters 2 are prepared. 9 can be hydrolyzed under acldlc conditions to glve 5-alkylldene-2(SH)-furan%es lo. Reaction of 1,2-hyd