A convenient synthesis of 3-functionalized 5-alkoxymethyl- and 5-phenoxymethyl-2(5H)-furanones and their transformations into related epoxy and methylene lactones
β Scribed by Vladimir I. Tyvorskii; Alexander S. Kukharev; Oleg G. Kulinkovich; Norbert De Kimpe; Kourosch Abbaspour Tehrani
- Book ID
- 104208304
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 422 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0040-4020
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β¦ Synopsis
A convenient procedure for the preparation of 3-functionalized 5-aikoxymethyl-and 5phenoxymethyl-2(SH)-furanones is described. The method is basedonthe condensation of various p-alkoxy-or ~-phenoxy-a-hydroxy ketones with ~activated esters in the presence of catalytic amounts of sodium methoxide. Results are reported showing the possible transformations of these 2(5H)furanones into related epoxy and a-methylene laetones.
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