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A convenient synthesis of 1,1,1,3,3,3-hexaphenyldiplumbathiane and 1,1,1,3,3,3-hexaphenyldiplumbaselenane

✍ Scribed by Bahr, Steven R.; Boudjouk, Philip


Book ID
127346963
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
270 KB
Volume
31
Category
Article
ISSN
0020-1669

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A convenient synthesis of 1,3-dithioles,
✍ R. S. Sukhai; W. Verboom; J. Meijer; M. J. M. Schoufs; L. Brandsma 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 341 KB

## Abstract Reaction of 1‐(chloromethylthio)‐1‐alkynes (RCCSCH~2~Cl, R  alkyl or phenyl) with an alkali metal sulfide, selenide or telluride gives 4‐substituted 1,3‐dithioles together with the corresponding 1,3‐thiaselenoles and 1,3‐thiatelluroles in good yields. The compounds RCCSCH~2~Cl ca