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A convenient preparation of “Free” sulfilimines by hydrolysis of N-p-tosylsulfilimines in sulfuric acid

✍ Scribed by Naomichi Furukawa; Tetsuo Omata; Toshiaki Yoshimura; Tetsuo Aida; Shigeru Oae

Book ID
104236676
Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
187 KB
Volume
13
Category
Article
ISSN
0040-4039

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✦ Synopsis

The acid catalyzed hydrolysis of aryl methyl N-p-tosylsulfilimines has been known to give the corresponding sulfoxides. l) However, the mechanism of the reaction has been unexplored. In order to understand in detail the

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A convenient preparation of N- (arenesul
A convenient preparation of N- (arenesulfonyl) sulfoximines by oxidation of N- (arenesulfonyl) sulfilimines with sodium hypochlorite in a two phase system
✍ Naomichi Furukawa; Kunihiko Akutagawa; Toshiaki Yoshimura; Shigeru Oae 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 215 KB

Sulfoximines are attractive organic sulfur compounds as alkylidene or chiral transfer reagent like sulfur ylides. 1) For example, Johnson et al. revealed that cc-sodio derivatives of N-(arenesulfonyl)sulfoximines are useful nucleophilic alkylidene transfer reagents, e.g., for the conversion of aldeh