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Unusually ready hydrolysis of nitrile groups in 1,1,2,2-tetracyanoethane by pyruvic acid

✍ Scribed by O. E. Nasakin; V. V. Pavlov; A. N. Lyshchikov; P. M. Lukin; V. N. Khrustalev; M. Yu. Antipin


Book ID
105534807
Publisher
Springer US
Year
1997
Tongue
English
Weight
236 KB
Volume
33
Category
Article
ISSN
0009-3122

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## An unexpected (1,2) Wittig rearrangement occurs upon photodecarboxylation of fenofibric acid in neutral aqueous medium, by contrast with the usual experimental conditions employed in this type of rearrangement (alkyllithiums in dry THF or ethyl ether). Solvent effects suggest a mechanism invohr