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A convenient, mild method for oxidative cleavage of alkenes with Jones reagent/osmium tetraoxide

โœ Scribed by Henry, James R.; Weinreb, Steven M.


Book ID
119994499
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
121 KB
Volume
58
Category
Article
ISSN
0022-3263

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Osmium tetraoxide has been demonstrated to be a highly efficient catalyst for the chemoselective oxidation of a variety of sulfides to the corresponding sulfones. Tertiary amine catalysis appears to play a key role in the reaction. Although considerable effort has been expended on the development o