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A Convenient Methodology for the N-Alkylation of Isatin Compounds

✍ Scribed by Garden, Simon J.; Torres, José C.; da Silva, Leonardo E.; Pinto, Angelo C.

Book ID
120046519
Publisher
Taylor and Francis Group
Year
1998
Tongue
English
Weight
441 KB
Volume
28
Category
Article
ISSN
0039-7911

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Reaction between alkyl isocyanides and d
Reaction between alkyl isocyanides and dialkyl acetylenedicarboxylates in the presence of N-alkyl isatins: convenient synthesis of γ-spiro-iminolactones
✍ Abbas Ali Esmaeili; Masoomeh Darbanian 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 109 KB

The highly reactive 1:1 intermediate generated in the reaction between an alkyl isocyanide and a dialkyl acetylenedicarboxylate is trapped by N-alkyl isatin to yield iminolactones in fairly high yields.