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A convenient method for the synthesis of N2,N2-dimethylguanosine by reductive carbon-sulfur bond cleavage with tributyltin hydride

✍ Scribed by Sekine, Mitsuo; Satoh, Takahiko


Book ID
120439800
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
507 KB
Volume
56
Category
Article
ISSN
0022-3263

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A mild and rapid method was found for the reductive cleavage of the carbon-sulfur bond in the alkylthiocyanates by samarium/Cp 2 TiCl 2 system to give the corresponding dialkyl disulfides in moderate to good yields.