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A convenient dehydrogenation reagent: Trityl triflouroacetate generated in situ

✍ Scribed by Peter P. Fu; Ronald G. Harvey

Book ID
104242988
Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
203 KB
Volume
15
Category
Article
ISSN
0040-4039

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Zerovalent nickel reagents offer prolific new areas of synthetic organic methodology. Bis(l,S-cyclooctadiene)nickel(O) [Ni(COD)2] and tetrakis(triphenylphosphine)nickel(O) [Ni(TPP)4] have mediated the symmetric coupling of aryllatb and vinyl2 halides. However, these sensitive reagents are convention