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A continuous pervaporation membrane reactor for the study of esterification reactions using a composite polymeric/ceramic membrane

✍ Scribed by Y. Zhu; R.G. Minet; T.T. Tsotsis


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
808 KB
Volume
51
Category
Article
ISSN
0009-2509

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✦ Synopsis


The esterification reaction between acetic acid and ethanol was studied in a continuous flow pervaporation membrane reactor utilizing a polymeric/ceramic composite membrane. For a range of experimental conditions reactor conversions were observed which are higher than the corresponding calculated equilibrium values. This is due to the ability of the membrane to remove water, a product of the reaction. A theoretical model has been developed which gives a reasonable fit of the experimental results.


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## Abstract A simulation of a membrane reactor for the water gas shift reaction is carried out by means of a 1D pseudo‐homogeneous nonisothermal mathematical model. The composite membrane consists of a dense layer of Pd (selective to H~2~) supported over a porous ceramic layer. The effect of temper