✦ LIBER ✦

A consideration of the ruby laser-induced decomposition of azoethane

✍ Scribed by D.L. Rousseau; W.E. Falconer; G.E. Leroi

Publisher: Elsevier Science
Year: 1972
Tongue: English
Weight: 455 KB
Volume: 13
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(72)80038-1

No coin nor oath required. For personal study only.

✦ Synopsis

Ruby lzzr-induced decomposition of azoethane 'mvg products different from the near W photodikciation.

:....:

Therefore, although in some experiments product yields varied quaiiratically wie la&r pow&i_, the principal diss&ia~ : ': -.

tion was not via two-photon photoexci+tion.

The two-photon photodissociation crass section is <. 10LT2 &n4 tic ;, . . ., ..

📜 SIMILAR VOLUMES

Laser-induced two-photon decomposition o

Laser-induced two-photon decomposition of azoethane

✍ S. Speiser; I. Oref; T. Goldstein; S. Kimel 📂 Article 📅 1971 🏛 Elsevier Science 🌐 English ⚖ 269 KB

Aznethanc undergoes two-photon photodissociation when irradbted by a Q-switched ruby Laser. The two-photon nature of the process is demon&a&d quantitatively for the fit time in a gas-phase reaction. The absorption cross section is found to be 6 = (6.5 f. 2.5) X 10-52 cm+ seclphoton molecule. Laser-

CO2 laser-induced decomposition of ethan

CO2 laser-induced decomposition of ethanol

✍ K. A. Holbrook; G. A. Oldershaw; C. J. Shaw 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 419 KB 👁 1 views

## Abstract The multiple photon absorption and decomposition of ethanol irradiated by pulsed 9P18 infrared radiation (1048.7 cm^−1^) from a TEA CO~2~ laser has been studied in the fluence range 15 to 5 J cm^−2^. The absorption cross‐section is pressure‐dependent due to rapid collisional rotational

Infrared laser-induced decomposition of

Infrared laser-induced decomposition of 2,2-dimethyloxetane

✍ K. A. Holbrook; C. J. Shaw; G. A. Oldershaw; P. E. Dyer 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 931 KB

The unimolecular decomposition of 2,2 dimethyloxetane to give either isobutene and formaldehyde or ethene and acetone induced by a pulsed C 0 2 laser has been investigated. Absorption characteristics and fractional decomposition have been studied as a function of laser fluence, irradiation frequency

The intensity dependence of ruby laser-i

The intensity dependence of ruby laser-induced photoionization of biphenyl radical anion

✍ G.Makkes van der Deijl; J. Dousma; S. Speiser; J. Kommandeur 📂 Article 📅 1973 🏛 Elsevier Science 🌐 English ⚖ 481 KB

Handbook of Laser-Induced Breakdown Spec

Handbook of Laser-Induced Breakdown Spectroscopy (Cremers/Handbook of Laser-induced Breakdown Spectroscopy) || Appendix A: Safety Considerations in LIBS

✍ Cremers, David A.; Radziemski, Leon J. 📂 Article 📅 2006 🏛 John Wiley & Sons, Ltd 🌐 English ⚖ 63 KB

Continuous-wave CO2 laser-induced SF6-se

Continuous-wave CO2 laser-induced SF6-sensitized decomposition of chloroalkanes

✍ K. A. Holbrook; G. A. Oldershaw; M. Matthews 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 248 KB

It has recently been suggested [ll that when l,l,l-trichloroethane is irradiated with a continuous-wave COP laser in the presence of SF6 sensitizer, the decomposition occurs in a molecular manner, viz. CH3CC13 4 CHZ = CCl2 + HC1 rather than by a radical-chain mechanism CHBCC13 CH3 -CC12 + C1 C1 + CH