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A Configuration-Retaining α, β-Diol to 1,4-Dioxane Conversion1

✍ Scribed by N. G. C. Hosten; D. Tavernier; M. J. O. Anteunis

Book ID
101767876
Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
216 KB
Volume
94
Category
Article
ISSN
0037-9646

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✦ Synopsis

givesrhe wno-Chalkylation product which cyAizes readily to the lactone(diournone) .

chemical deoxygbtion with trichlorosilane affords the dioxane derivative perhydro-l.4dioxaanthracene.

Cis-Perhydronaphtalene-2.3-diol treated with ethyl diaroacetate/rhodir(II) pivalate

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📜 SIMILAR VOLUMES

New Olefinic Cyclizations by Oxymetallat
New Olefinic Cyclizations by Oxymetallation. Conversion of (−)-elemol to (−)-selina-4α, 11-diol (cryptomeridiol) and (−)-guai-1 (10)-ene-4α, 11-diol
✍ Walter Renold; Günther Ohloff; Torbjörn Norin 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 German ⚖ 545 KB

## Abstract Acetoxythallation of (−)‐elemol acetate (**1b**) yields a diacetate **2b** which after treatment with lithium aluminium hydride gives (−)‐guai‐1 (10)‐ene‐4α, 11‐diol (**2a**). (−)‐Elemol (**1a**) is converted to (−)‐selina‐4α, 11‐diol (**9**, cryptomeridiol) by hydroxymercuration follow