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A concise synthesis of α-glycosyl cyanides

✍ Scribed by Yasuhiro Igarashi; Tatsushi Shiozawa; Yoshitaka Ichikawa

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
257 KB
Volume
7
Category
Article
ISSN
0960-894X

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✦ Synopsis

A simple procedure has been developed for the synthesis of c~-glycosyl cyanides: reactions of O-benzylated ethyl 1-thio-glycosides of L-fucose and D-glucose, with TMSCN and MeOTf in ether exclusively gave the corresponding ec-glycosyl cyanides in good yields.

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