## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Diastereoselective synthesis of glycosyl-α-aminoacids
✍ Scribed by Samira Bouifraden; Jean-Pierre Lavergne; Jean Martinez; Philippe Viallefont; Claude Riche
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 336 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0957-4166
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✦ Synopsis
Asymmetric synthesis of various glycosyl-ct-aminoacids is described. The approach involves the diastereoselective condensation of glycine enolates on the carbonyl in position 3 of the suitably protected et-D-ribohexofuranos-3-ulose.
📜 SIMILAR VOLUMES
3-Alkoxy ~x-aminoacid esters and N-hydroxy a-amino esters are obtained by the reduction of easily accessible ~-oximino esters.
## Abstract For Abstract see ChemInform Abstract in Full Text.
A new strategy for assembly of glycosyl a-aminoacids via the stereocontrolled buildup of a serine-derived penaldic acid equivalent (i.e. I + II) is illustrated by the asymmetric synthesis of thymine polyoxin C.