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A Concise and Versatile Synthesis of Alkaloids from Kopsia tenuis : Total Synthesis of (±)-Lundurine A and B

✍ Scribed by Arai, Shigeru; Nakajima, Masaya; Nishida, Atsushi

Book ID: 121856053
Publisher: John Wiley and Sons
Year: 2014
Tongue: English
Weight: 601 KB
Volume: 53
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.201400464

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## Abstract The total synthesis of the diarylheptanoids (−)‐diospongin A (**1**) and B (**2**) was achieved stereoselectively __via__ the __δ__‐lactone intermediate **6**. The key reactions involved are a stereoselective reduction of __β__‐keto ester and the __Horner–Wadsworth–Emmons__ and intramol