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Concise total synthesis of phidianidine A and B

✍ Scribed by Buchanan, Jacob C.; Petersen, Brandon P.; Chamberland, Stephen

Book ID
121269975
Publisher
Elsevier Science
Year
2013
Tongue
French
Weight
439 KB
Volume
54
Category
Article
ISSN
0040-4039

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## Abstract The total synthesis of the diarylheptanoids (βˆ’)‐diospongin A (**1**) and B (**2**) was achieved stereoselectively __via__ the __Ξ΄__‐lactone intermediate **6**. The key reactions involved are a stereoselective reduction of __Ξ²__‐keto ester and the __Horner–Wadsworth–Emmons__ and intramol