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A Computationally Designed Rh(I)-Catalyzed Two-Component [5+2+1] Cycloaddition of Ene-vinylcyclopropanes and CO for the Synthesis of Cyclooctenones

✍ Scribed by Wang, Yuanyuan; Wang, Jingxin; Su, Jiachun; Huang, Feng; Jiao, Lei; Liang, Yong; Yang, Dazhi; Zhang, Shiwei; Wender, Paul A.; Yu, Zhi-Xiang

Book ID: 126064162
Publisher: American Chemical Society
Year: 2007
Tongue: English
Weight: 57 KB
Volume: 129
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja072505w

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## Abstract The unexpected and unprecedented reaction affords cyclopenta‐, pyrrolo‐, or furo‐fused indanediones with one or two adjacent bridgehead quaternary all‐carbon stereocenters.