ChemInform Abstract: Rh(I)-Catalyzed Formal [5 + 1]/[2 + 2 + 1] Cycloaddition of 1-Yne-vinylcyclopropanes and Two CO Units: One-Step Construction of Multifunctional Angular Tricyclic 5/5/6 Compounds.

✍ Scribed by Mu Lin; Feng Li; Lei Jiao; Zhi-Xiang Yu

• Publisher: John Wiley and Sons
• Year: 2011
• Weight: 100 KB
• Volume: 42
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.201122025

✦ Synopsis

Abstract

The unexpected and unprecedented reaction affords cyclopenta‐, pyrrolo‐, or furo‐fused indanediones with one or two adjacent bridgehead quaternary all‐carbon stereocenters.