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A computational approach to intermolecular proton transfer in the solid state: assistance by proton acceptor molecules

✍ Scribed by Alkorta, Ibon; Rozas, Isabel; Elguero, José


Book ID
121309039
Publisher
Royal Society of Chemistry
Year
1998
Tongue
English
Weight
191 KB
Volume
12
Category
Article
ISSN
1472-779X

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Using dynamic 15N CPMAS NMR spectroscopy a novel double proton transfer was detected in the cyclic hydrogen bonded dimers of polycrystalline tSN,ZSN'-di-(4-bromophenyl)-formamidine. Rate constants of this process, which is degenerate within the margin of error, were obtained by lineshape (kl2 = 10 6