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Observation of a nonconcerted double proton transfer in the solid state by nitrogen-15 CPMAS NMR

✍ Scribed by Limbach, H. H.; Wehrle, B.; Zimmermann, H.; Kendrick, R. D.; Yannoni, C. S.


Book ID
127382262
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
282 KB
Volume
109
Category
Article
ISSN
0002-7863

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Observation and characterization by 15N
✍ Ferdinand MΓ€nnle; Iwona Wawer; Hans-Heinrich Limbach πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 378 KB

Using dynamic 15N CPMAS NMR spectroscopy a novel double proton transfer was detected in the cyclic hydrogen bonded dimers of polycrystalline tSN,ZSN'-di-(4-bromophenyl)-formamidine. Rate constants of this process, which is degenerate within the margin of error, were obtained by lineshape (kl2 = 10 6