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A Comprehensive Kinetic Model of Free-Radical-Mediated Interfacial Polymerization

✍ Scribed by Shenoy, Raveesh; Bowman, Christopher N.


Book ID
126264583
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
459 KB
Volume
22
Category
Article
ISSN
1022-1344

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## Abstract Controlled/living radical polymerization systems in which the active period is extremely small, __Ο•__~A~ β‰ͺ 1, such as the cases of stable free radical mediated polymerization (or nitroxide mediated polymerization) and atom transfer radical polymerization, are considered theoretically. T

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An integral relationship, first given by Nishimura, has been applied to the bulk and solution polymerizations (dead-end data) of ethyl methacrylate. The kinetic rate constants calculated by this method for the bulk and solution cases are compared. The results are also compared with those previously