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A complex containing a nickel-oxygen unit at the center of a porphyrin. The x-ray crystal and molecular structure of the nickel(II) complex of octaethylporphyrin N-oxide dianion

โœ Scribed by Balch, Alan L.; Chan, Yee Wai; Olmstead, Marilyn M.


Book ID
127171256
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
594 KB
Volume
107
Category
Article
ISSN
0002-7863

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The six-step synthesis of a chiral, pentadentate dihydrosalen ligand, carrying a mercaptomethyl group as additional binding site, is described. When this ligand was treated with nickel(I1) salts, a planar tetracoordinated nickel chelate was obtained, and not the expected pentacoordinated species. Th