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A Comparative Study of the Kinetics and Mechanism of Solid-Solid Reaction between Agl and Some Mixed Mercury Halides

✍ Scribed by M.A. Beg; Afaq Ahmad; Saba Beg

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
221 KB
Volume
105
Category
Article
ISSN
0022-4596

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✦ Synopsis

The reaction of (\mathrm{AgI}) with mercuric chlorobronide and mercuric chloroiodide in solid state was studied by (\mathrm{X})-ray diffraction, chemical analysis, and electrical conductivity measurements. The kinetics of the reaction has been studied by a visual technique. The data for the lateral diffusion best fit the equation (X^{n}=k t). Both of the reactions are diffusion controlled and proceed via vapor phase diffusion of the mixed mercury halides. The reaction with (\mathrm{HgClI}) is somewhat simple that with (\mathrm{HgClBr}) is a complex one. 1993 Academic Press. Inc.

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