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A Comparative Study of the Alkaline Hydrolysis of o-Hydroxy-α-toluenesulfonic Acid Sultone and Phenyl α-Toluenesulfonate

✍ Scribed by Zaborsky, O. R.; Kaiser, E. T.


Book ID
125495689
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
469 KB
Volume
88
Category
Article
ISSN
0002-7863

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## Abstract The oxidation of α‐hydroxy acids and α‐hydroxy ketones by Br(V) follows the rate‐law However, the former reaction exhibits a second‐order dependence on hydrogen ion concentration while the latter reaction has a third‐order dependence. A mechanism involving a slow formation of a bromate