This paper studies the use of 5% (wt) citric acid without inhibitor, inhibited with benzotriazole (BTA) and 2-amino-5-mercapto-1,3,4thiadiazole (AMT) and de-aerated with nitrogen in the cleaning of 18th and 19th century chalcographic plates. DC and AC electrochemical techniques have been used to cha
A comparative study of benzotriazole and 2-amino-5-mercapto-1,3,4-thiadiazole as Copper corrosion inhibitors in acid media
✍ Scribed by Dr. J. M. Bastidas; E. Otero
- Publisher
- John Wiley and Sons
- Year
- 1996
- Tongue
- German
- Weight
- 455 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0947-5117
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✦ Synopsis
Abstract
In this paper the corrosion behaviour of copper in 5% (by weight) citric, sulphuric and hydrochloric acids is studied. The efficiency of 2‐amino‐5‐mercapto‐1,3,4‐thiadiazole (AMT) as a corrosion inhibitor is compared with the use of benzotriazole (BTA). The experimental techniques were weight loss, polarization curves, polarization resistance and electrochemical impedance spectroscopy. AMT showed greater inhibition efficiency than BTA in sulphuric and hydrochloric acids. In citric acid AMT and BTA show a similar behaviour.
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