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A Common Mechanism for Branching, Cyclopropanation, and Cyclobutanation Reactions in the Isoprenoid Biosynthetic Pathway

✍ Scribed by Thulasiram, Hirekodathakallu V.; Erickson, Hans K.; Poulter, C. Dale

Book ID: 126153695
Publisher: American Chemical Society
Year: 2008
Tongue: English
Weight: 162 KB
Volume: 130
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja0771282

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## Abstract __Experimental and theoretical investigations concerning the second‐to‐last step of the DXP/MEP pathway in isoprenoid biosynthesis in plants are reported. The proposed intrinsic or late intermediates 4‐oxo‐DMAPP (__**__12__**__) and 4‐hydroxy‐DMAPP (__**__11__**__) were synthesized in d