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A comment on the equilibrium of Si3N4 + 3C ⇄ 3SiC + 2N2

✍ Scribed by A. Kato; H. Mizumoto; Y. Fukushige

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
235 KB
Volume
10
Category
Article
ISSN
0272-8842

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✍ Nadine Götz; Sebastian Herler; Peter Mayer; Axel Schulz; Alexander Villinger; Ja 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 187 KB

## Abstract The Staudinger reactions of SP(N~3~)~3~ (1) with 1, 2 and 3 equiv. of triphenylphosphane PPh~3~ and (TMS)~2~N–(TMS)N–PPh~2~ (2) have been investigated (TMS = Me~3~Si). Reaction with PPh~3~ yields the single and double Staudinger products SP(N~3~)~2~NPPh~3~ (3) and SP(N~3~)(NPPh~3~)~2~ (