A Combined Gas-Phase, Solution-Phase, and Computational Study of C−H Activation by Cationic Iridium(III) Complexes
✍ Scribed by Hinderling, Christian; Feichtinger, Derek; Plattner, Dietmar A.; Chen, Peter
- Book ID
- 127136429
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 415 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0002-7863
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Fast-atom bombardment mass spectrometry has been used to investigate the chemical behavior of Fe(III) and Mn(III) tetraarylporphyrins (TAP) in both the condensed and gas phases and to clarify the mechanisms responsible for the production of positive and negative ions. The differences in the behavior
The chemical behavior of Fe(III) and M(III) tetraarylporphorin (TAP) complexes with N-alkylimidazoles and other suitable ligands was studied by direct reaction in the fast-atom bombardment matrix and in the gas phase. The coordination reaction occurs at the metal center and yields molecular adducts