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A study on the solution and gas-phase chemistry of Mn(III) and Fe(III) tetraarylporphyrin complexes by fast-atom bombardment mass spectrometry

✍ Scribed by Federico Maria Rubino; Stefano Banfi; Gianluca Pozzi; Quici Silvio

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 380 KB
Volume: 4
Category: Article
ISSN: 1044-0305
DOI: 10.1016/1044-0305(93)85089-g

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✦ Synopsis

The chemical behavior of Fe(III) and M(III) tetraarylporphorin (TAP) complexes with N-alkylimidazoles and other suitable ligands was studied by direct reaction in the fast-atom bombardment matrix and in the gas phase. The coordination reaction occurs at the metal center and yields molecular adducts of porphyry/ligand (PL) and PL, stoichiometry. Coordinative competition between free and covalently linked ligands can be used to probe the conformation of "tailed" Mn(III)-TAP.

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