A flash photolysis-shock tube technique is described for making kinetic measurements a t high temperature. Coupled with sensitive atomic resonance absorption detection, this method allows bimolecular rate constants for atom-molecule reactions to be measured directly under conditions free from kineti
A Combined Flash-Photolysis, Shock-Tube Technique for the Study of Fast Photochemical Reactions
β Scribed by Bradley, J. N.; Tuffnell, R.
- Book ID
- 120144302
- Publisher
- The Royal Society
- Year
- 1964
- Tongue
- English
- Weight
- 618 KB
- Volume
- 280
- Category
- Article
- ISSN
- 0962-8444
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A new method involving the use of flash photolysis followed by rapid high performance liquid chromatography analysis is described and applied to the examination of the photodegradation of 4-chlorophenol (I) in aerated aqueous solution (6.3~ lop4 M). Analysis after a single flash indicates that p-ben