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A Combined Experimental and Theoretical Study of Sulfur Oxyfluoride Anion and Neutral Thermochemistry and Reactivity †

✍ Scribed by Arnold, Susan T.; Miller, Thomas M.; Viggiano, A. A.


Book ID
127380854
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
143 KB
Volume
106
Category
Article
ISSN
1089-5639

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Salts with the Triborate Anion [B3O3F2(O
✍ Maik Finze; Guido J. Reiss 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 239 KB

## Abstract Reactions of [3‐NC‐B~11~F~10~]^2–^ with aqueous bases resulted in a cluster degradation. From the reaction mixtures, salts of the [B~3~O~3~F~2~(OH)~2~]^–^ anion (1) with [Ph~4~P]^+^ or [Ph~3~MeP]^+^ as countercations were isolated. Both salts were investitgated by single‐crystal X‐ray d