𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A Combined Experimental and Theoretical Study of Anion–π Interactions in Bis(pyr­imidine) Salts

✍ Scribed by Angel Garcia-Raso; Francisca M. Albertí; Juan J. Fiol; Andrés Tasada; Miquel Barceló-Oliver; Elies Molins; Daniel Escudero; Antonio Frontera; David Quiñonero; Pere M. Deyà


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
478 KB
Volume
2007
Category
Article
ISSN
1434-193X

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


A Theoretical Study of Anion–π Interacti
✍ David Quiñonero; Antonio Frontera; Daniel Escudero; Pablo Ballester; Antonio Cos 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 410 KB

## Abstract Several complexes of tropylium (**1**) with anions are optimized at the RI‐MP2(full)/6‐31++G\*\* level of theory. This binding unit can interact very favorably with anions, and it combines the strength of the electrostatic interaction with the directionality of the anion–π interaction.

Salts with the Triborate Anion [B3O3F2(O
✍ Maik Finze; Guido J. Reiss 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 239 KB

## Abstract Reactions of [3‐NC‐B~11~F~10~]^2–^ with aqueous bases resulted in a cluster degradation. From the reaction mixtures, salts of the [B~3~O~3~F~2~(OH)~2~]^–^ anion (1) with [Ph~4~P]^+^ or [Ph~3~MeP]^+^ as countercations were isolated. Both salts were investitgated by single‐crystal X‐ray d