𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A cogwheel effect in the internal rotations of highly hindered systems

✍ Scribed by Kwart, Harold.; Alekman, Stanley.


Book ID
126003812
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
285 KB
Volume
90
Category
Article
ISSN
0002-7863

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A simple approximation for the vibration
✍ Donald G. Truhlar πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons 🌐 English βš– 455 KB

A simple formula is presented for calculating the approximate partition function of a hindered internal rotational mode of a polyatomic molecule. The formula gives useful accuracy over the whole range from harmonic oscillator to hindered rotator to free rotator