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A classical sudden approximation for vibrational predissociation of the van der Waals molecules. Application to He…I2 complex

✍ Scribed by N. Martin; P. Mareca; P. Villarreal; G. Delgado-Barrio

Book ID
119116459
Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
376 KB
Volume
120
Category
Article
ISSN
0166-1280

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✍ G. Delgado-Barrio; P. Villarreal; P. Mareca; J. A. Beswick 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 399 KB

We study the vibrational predissociation of the van der Waals molecule Ne . . 12(B3v) by Using a quasiclassical trajectory method. The potential energy surface assumed was a simple sum of pairwise atom-atom interactions. According to approximate quantal calculations, the necessary initial conditions

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Vibrational predissociation of highly vibrationally excited van der Waals molecules. A quantum-mechanical distorted-wave treatment for vibration and sudden approximation for rotation
✍ M. Aguado; P. Villarreal; G. Delgado-Barrio; P. Mareca; J.A. Beswick 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 451 KB

In this paper a three-dimensional quantum model to study vibrational predissociation of van der Waals molecules is applied to the +-He complex for very high vibrational (SO 4 ~14 64) of the 12 subunit The vibrations are described in the distorted-wave diabatic approximation while rotations are treat