We advance a theoretical model for wbrational predissociation (VP) of a linear triatomic molecular comple\ consistmg of a rare-gas atom bound to a diatomic, which rests on the decay of a bound state into a mnnรฏfold of coupled translational continua. We explored the dependence of the VP :ate on the m
The mechanical origin of the propensity rule for vibrational predissociation of van der Waals molecules
โ Scribed by Daniel A. Morales
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 896 KB
- Volume
- 132
- Category
- Article
- ISSN
- 0301-0104
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๐ SIMILAR VOLUMES
In this paper a three-dimensional quantum model to study vibrational predissociation of van der Waals molecules is applied to the +-He complex for very high vibrational (SO 4 ~14 64) of the 12 subunit The vibrations are described in the distorted-wave diabatic approximation while rotations are treat
The relaxation kinetics of N20 and CO2 vibrationally exited molecules (VEhl) in two-phase gas-cluster systems was investigated under conditions of supersonic expansion with condensation. The catalytic effect of clusters on the vibrational relaxation rate was revealed. The relaxation rate of clustere