A clarification of the factors governing the stability of rx- radical anions
β Scribed by Jih Tzong Wang; Ffrancon Williams
- Book ID
- 103016901
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 217 KB
- Volume
- 72
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The g-factors of the diphenylacetylene and diphenyldiacethylene anion radicals were measured and found to be 2.00264 and 2.00216 respectively. The unexpected difference behvveen these values is esplained by interaction of the phenyl groups with the acetylene p-orbitals.
## Abstract The radical anions of 6aβthiathiophthenes ([1,2]dithiolo[1,5β__b__] [1,2]dithioles), I(R), convert into those of 4__H__βthiapyranβ4βthiones, III(R), via __cis__β__trans__ isomerization. The reaction is slowed down when the size of the substituent R in the 2,5βpositions of 6aβthiathiopht