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A Chromium Ethylidene Complex as a Potent Catalyst for Selective Ethylene Trimerization

✍ Scribed by Dr. Sebastiano Licciulli; Khalid Albahily; Valeria Fomitcheva; Dr. Ilia Korobkov; Prof. Dr. Sandro Gambarotta; Dr. Robbert Duchateau


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
324 KB
Volume
50
Category
Article
ISSN
0044-8249

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✍ Stephan Peitz; Normen Peulecke; Bhaskar R. Aluri; Sven Hansen; Bernd H. Müller; 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 342 KB

## Abstract In this paper a novel ligand of the type [PNPNH] is presented for the application in a new homogeneous highly selective ethene trimerization system for the formation of 1‐hexene, which consists of the chromium source CrCl~3~(thf)~3~, the ligand Ph~2~PN(__i__Pr)P(Ph)N(__i__Pr)H (1), and