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A Bimetallic Ruthenium Ethylene Complex as a Catalyst Precursor for the Kharasch Reaction.

✍ Scribed by Laurent Quebatte; Euro Solari; Rosario Scopelliti; Kay Severin

Publisher
John Wiley and Sons
Year
2005
Weight
24 KB
Volume
36
Category
Article
ISSN
0931-7597

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## Abstract The bimetallic ruthenium complex [(1,3,5‐__i__‐Pr~3~C~6~H~3~)Ru(μ‐Cl)~3~RuCl(C~2~H~4~)(PCy~3~)] has been synthesized by reaction of [(1,3,5‐__i__‐Pr~3~C~6~H~3~)RuCl~2~)]~2~ with one equivalent of PCy~3~ in the presence of ethylene. It can be used as a catalyst precursor for the controll